Study on Crack Propagation in Proton Exchange Membranes with Doped Microcapsules

نویسندگان

چکیده

Abstract Crack defects produced during the operation of proton exchange membrane fuel cells (PEMFCs) have a significant impact on their service life. One common approach to extend working time is embed self-healing microcapsules in repair defects. In this study, we use extended finite element method (XFEM) investigate capture and control cracks by doped numerically simulate crack propagation patterns. The results show that two-layer microcapsule distribution along cross-section can achieve complete cracks. addition, two-material with layered, staggered arrangement exhibit maximum distance between they attract, while minimizing mechanical properties membrane. Based these findings, determine theoretical doping amount per unit volume, which has important implications for future experimental design engineering applications.

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Novel PVA/La2Ce2O7 hybrid nanocomposite membranes for application in proton exchange membrane fuel cells

Proton exchange membrane fuel cells (PEMFCs) are electrochemical devices that show the highest power densities compared to the other type of fuel cell. In this work, nanocomposite membranes used for proton exchange membrane fuel cells as poly(vinyl alcohol)/La2Ce2O7 (PVA-LC) with the aim of increasing the water uptake and proton conductivity. Glutaraldehyde (GA) was used as cross linking agent ...

متن کامل

Propagation of Crack in Linear Elastic Materials with Considering Crack Path Correction Factor

Modeling of crack propagation by a finite element method under mixed mode conditions is of prime importance in the fracture mechanics. This article describes an application of finite element method to the analysis of mixed mode crack growth in linear elastic fracture mechanics. Crack - growth process is simulated by an incremental crack-extension analysis based on the maximum principal stress c...

متن کامل

Molecular Dynamics Simulations of Proton Transport in Proton Exchange Membranes Based on Acid-Base Complexes

Proton exchange membrane fuel cells (PEMFCs) are promising energy conversion devices for the future society for their high energy conversion efficiency, environmental friendliness, and structural compactness. Therefore, PEMFCs have attracted great attention from academic and industry institutions; and billions of dollars of research funding from both private organizations and governmental agenc...

متن کامل

Methanol crossover and selectivity of nafion/heteropolyacid/montmorillonite nanocomposite proton exchange membranes for DMFC applications

In this work, we prepared the nafion/montmorillonite/heteropolyacid nanocomposite membranes for direct methanol fuel cells (DMFCs). The analyses such as X-ray diffraction (XRD), Fourier transform infrared (FTIR), and scanning electron microscopy (SEM) were conducted to characterize the filler dispersion and membrane structure in prepared nanocomposite membranes. XRD patterns of nafion-CsPW-MMT ...

متن کامل

State of Water in Perfluorosulfonic Ionomer (Nafion) Proton Exchange Membranes

This manuscript reports on the direct identification of four states of water in hydrated Nafion ionomer polymers, including a quantitative measurement of their dynamics, as previously published in the Journal of the Electrochemical Society, 155, B163-B171 (2008). Here, we provide further details on the dynamics of these water states and we underline still-open scientific questions, towards stim...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Journal of physics

سال: 2023

ISSN: ['0022-3700', '1747-3721', '0368-3508', '1747-3713']

DOI: https://doi.org/10.1088/1742-6596/2578/1/012020